in electron transfer involving a metallic atom and an

Electrochemical charge transfer at a metallic electrode: A simulation Uncovering near-free platinum single-atom dynamics during electrochemical hydrogen evolution reaction. Int. 140, 1619816205 (2018). electron transfer reactions at metal electrodes. : Porous heterostructured MXene/carbon nanotube composite paper with high volumetric capacity for sodium-based energy storage devices. Metallic bonds (video) | Khan Academy Soc. Copyright 2019, Springer Nature. Energy Mater. Nat. Int. 31, 1801526 (2019). 5, 673689 (2018). Nat. : Metal-organic-framework-derived hollow N-doped porous carbon with ultrahigh concentrations of single Zn atoms for efficient carbon dioxide conversion. Int. Hannagan, R. T. et al. Int. 141, 93059311 (2019). 134, 89688974 (2012). Catal. https://doi.org/10.1038/s41929-018-0195-1, Huang, B., Li, N., Ong, W.J., et al. Chem. Ledezma-Yanez, I. et al. ACS Appl. Article Highly active and stable metal single-atom catalysts achieved by strong electronic metalsupport interactions. Am. Adv. J. 139, 93419349 (2017). Commun. Nat. J. Electroanal. : Single atoms and clusters based nanomaterials for hydrogen evolution, oxygen evolution reactions, and full water splitting. Commun. Chem. 9, 52235230 (2019). 9, 810816 (2017). https://doi.org/10.1002/anie.201803272, Harzandi, A.M., Shadman, S., Nissimagoudar, A.S., et al. 11, 2455 (2020). Chem. Angew. Int. Chem. Ed. Chem. 17, 10331039 (2018). https://doi.org/10.1002/smtd.201800406, Wang, L.X., Wang, L., Meng, X.J., et al. 1, 531539 (2018). Chem. Anniyev, T. et al. Google Scholar. 10, 44364447 (2017). The electron-electron scattering due to the large electron oscillation of LSPR causes the fast decay of the electronic excitation in ~10 fs. https://doi.org/10.1016/j.jechem.2020.02.020, Li, J.Z., Chen, M.J., Cullen, D.A., et al. 19, 63856397 (2013). https://doi.org/10.1021/jp210241c, Daelman, N., Capdevila-Cortada, M., Lpez, N.: Dynamic charge and oxidation state of Pt/CeO2 single-atom catalysts. 10, 4500 (2019). Angew. Angew. : Confined pyrolysis within a nanochannel to form a highly efficient single iron site catalyst for Zn-air batteries. Single-atom catalysis of CO oxidation using Pt1/FeOx. Nano Res. Soc. 4, 39003912 (2011). Mater. Nanotechnol. : First principles and machine learning based superior catalytic activities and selectivities for N2 reduction in MBenes, defective 2D materials and 2D -conjugated polymer-supported single atom catalysts. 58, 1093210935 (2019). : New strategies for the preparation of sinter-resistant metal-nanoparticle-based catalysts. : Single-atom Pt in intermetallics as an ultrastable and selective catalyst for propane dehydrogenation. Int. : Hydrogen evolution: high-performance hydrogen evolution by Ru single atoms and nitrided-Ru nanoparticles implanted on N-doped graphitic sheet. Energy Environ. Constable, E. C., Henney, R. P. G., Leese, T. A. Chem. Mater. Chem. Technol. 142, 24482459 (2020). https://doi.org/10.1021/acsami.8b14616, Chen, S.C., Chen, Z.H., Siahrostami, S., et al. Maestri, M. et al. https://doi.org/10.1002/anie.201109257, Shen, H.J., Gracia-Espino, E., Ma, J.Y., et al. Hu, P. et al. https://doi.org/10.1038/s41467-018-04501-4, Pereira-Hernndez, X.I., DeLaRiva, A., Muravev, V., et al. : CO tolerance of Pd-rich platinum palladium carbon-supported electrocatalysts. J. https://doi.org/10.1002/adma.201900509, Xiao, M.L., Zhu, J.B., Li, G.R., et al. : Termination effects of Pt/v-Tin+1CnT2 MXene surfaces for oxygen reduction reaction catalysis. 607, 4753 (2013). Chem. https://doi.org/10.1021/ja049436v, Lei, Y., Mehmood, F., Lee, S., et al. 1, 385397 (2018). Chem. J. Phys. Lett. 10, 1743 (2019). A.K.-W.C. and E.Y.-H.H. Sodium and chlorine atoms provide a good example of electron transfer. Adv. Soc. : Bridging homogeneous and heterogeneous catalysis by heterogeneous single-metal-site catalysts. 140, 38763879 (2018). Am. 21771030) and the Natural Science Foundation of Liaoning Province (2020-MS-113). Greiner, M. T. et al. J. Phys. USA 113, 28452850 (2016). Nat. Figure : Mother and daughter Why Bonds Form http://creativecommons.org/licenses/by/4.0/, Single-atomic platinum on fullerene C60 surfaces for accelerated alkaline hydrogen evolution, Dopant triggered atomic configuration activates water splitting to hydrogen, An electron-hole rich dual-site nickel catalyst for efficient photocatalytic overall water splitting, A sodium-ion-conducted asymmetric electrolyzer to lower the operation voltage for direct seawater electrolysis, Location-selective immobilisation of single-atom catalysts on the surface or within the interior of ionic nanocrystals using coordination chemistry. 41, 30553066 (2002). : Highly efficient catalysis of preferential oxidation of CO in H2-rich stream by gold single-atom catalysts. Soc. Res. Nature 376, 238240 (1995). Am. Commun. : Coordination-controlled single-atom tungsten as a non-3d-metal oxygen reduction reaction electrocatalyst with ultrahigh mass activity. Chem. Chem. 134, 65206523 (2012). https://doi.org/10.1021/jacs.7b10394, Yu, Y.K., Qu, S.H., Zang, D.Y., et al. acknowledges support from the University of Hong Kong under the University Research Committee Strategically Oriented Research Theme on Functional Materials for Molecular Electronics. Kwok, W.-K. et al. Chem. J. Phys. Acc. Int. Central . Vayssilov, G. N. et al. In situ phosphatizing of triphenylphosphine encapsulated within metalorganic frameworks to design atomic Co1P1N3 interfacial structure for promoting catalytic performance. ChemNanoMat 3, 164167 (2017). 4, 12741278 (2014). 5, 62496254 (2015). 13, 50 (2018). Catal. Nat. https://doi.org/10.1038/s41565-018-0197-9, Zhu, C.Z., Shi, Q.R., Xu, B.Z., et al. The samples for ICP analysis were treated with aqua regia in Teflon-lined autoclaves at 230C for 12 h. The X-ray absorption spectroscopy at the Pt L3-edge was obtained at the 14W1 beam line of the Shanghai Synchrotron Radiation Facility, using a Si(111) double-crystal monochromator operated at 3.5GeV in fluorescence mode. Angew. : Iridium-triggered phase transition of MoS2 nanosheets boosts overall water splitting in alkaline media. https://doi.org/10.1039/c4cc01625d, Kou, Z.K., Zang, W.J., Pei, W., et al. 135, 1600216005 (2013). Sawa, A. Resistive switching in transition metal oxides. Mater. Article Mater. : Highly selective oxygen reduction to hydrogen peroxide on transition metal single atom coordination. : Insight of the stability and activity of platinum single atoms on ceria. Adv. 58, 1396113968 (2019). In this review, we track the recent advances in SACs from an MSI perspective. Phys. Nat. : Introducing structural sensitivity into adsorption-energy scaling relations by means of coordination numbers. https://doi.org/10.1016/j.apcatb.2020.119304, Chen, Y.J., Ji, S.F., Sun, W.M., et al. 4 quantum numbers: The state of an electron in an atom is described by a set of 4 quantum numbers principle quantum number n = 1, 2, 3, n subsidiary or azimuthal number L = 0, 1, 2, n-1 magnetic quantum number m L= 0, 1, 2, n-1 spin quantum number m S = 7. 58, 1073210736 (2019). : Defect-based single-atom electrocatalysts. [175]. ISSN 2397-3358 (online). Qin, R. et al. : Regulation of coordination number over single Co sites: triggering the efficient electroreduction of CO2. Nat. Chem. Google Scholar. Electrons can be shared with all atoms in a material. Chem. Angew. : Efficient metal-free electrocatalysts from N-doped carbon nanomaterials: mono-doping and co-doping. The near ambient-pressure XPS (NAP-XPS) experiments were performed by using a differentially pumped electron analyzer and an in situ ambient-pressure gas cell equipped with a twin anode X-ray source (SPECS XR50, Al K, h=1486.6 eV; Mg K, h=1253.6eV) under a base pressure at 0.5mbar. https://doi.org/10.1039/c3cs60026b, Kou, Z.K., Wang, T.T., Gu, Q.L., et al. 10, 1902844 (2020). 5, 24742478 (2014). Electronic metalsupport interactions in single-atom catalysts. 56, 1608616090 (2017). Radical cascade reactions triggered by single electron transfer - Nature Sci. https://doi.org/10.1002/anie.201702473, Wang, J., Huang, Z.Q., Liu, W., et al. Ed. 8, 88168829 (2018). Chem. Soc. Anyone you share the following link with will be able to read this content: Sorry, a shareable link is not currently available for this article. In electron transfer involving a metallic atom and a nonmetallic atom during ion formation, which of the following is correct? PubMed Angew. When two oxygen atoms bond, they become a molecule and don't interact much with other molecules. Chem. Catal. Am. 7, 403410 (2015). : Enhanced stability of Pt-Cu single-atom alloy catalysts: in situ characterization of the Pt/Cu(111) surface in an ambient pressure of CO. J. Phys. J. https://doi.org/10.1126/science.1085721, Bliem, R., McDermott, E., Ferstl, P., et al. Mater. https://doi.org/10.1021/jacs.7b10385, Chung, H.T., Cullen, D.A., Higgins, D., et al. Chem. RSC Adv. Sci. : Activation of surface lattice oxygen in single-atom Pt/CeO2 for low-temperature CO oxidation. Reprinted with permission from Ref. https://doi.org/10.1007/s12274-015-0796-9, Francs, L., Corby, S., Selim, S., et al. : Finding optimal surface sites on heterogeneous catalysts by counting nearest neighbors. Nat. A very common example is the transfer of an atom or a group B from AB to form BC Figure 2. Wang, X. et al. CoN2+2 is the more favorable configuration after comparison. Am. Sustain. https://doi.org/10.1038/ncomms10922, Kwon, H.C., Kim, M., Grote, J.P., et al. and Y.X. Chem. Evidence of intramolecular electron transfer between two metallic atoms ACS Catal. Mater. https://doi.org/10.1007/s12274-019-2351-6, Li, J., Tang, Y., Ma, Y., et al. Anyone you share the following link with will be able to read this content: Sorry, a shareable link is not currently available for this article. Energy Mater. Int. Group 8 noble metals supported on titanium dioxide. https://doi.org/10.1039/c6ta09887h, Zhang, L.P., Xia, Z.H. Appl. Barigelletti, F. et al. Chem. Energy Mater. The electrode was kept in this solution for more than 20 min at an open circuit potential to ensure a complete galvanic replacement of Cu by Pt(II), forming atomically dispersed Pt decorated ce-TMDs nanohybrid (termed as Pt-SAs/TMDs). Int. 136, 29522955 (2014). https://doi.org/10.1038/nmat4757, Golafrooz Shahri, S., Roknabadi, M.R., Radfar, R.: Spin-dependent structural, electronic and transport properties of armchair graphyne nanoribbons doped with single transition-metal atom, using DFT calculations. : Support effects in single-atom platinum catalysts for electrochemical oxygen reduction. B 81, 153406 (2010). J. Chem. For example, the outermost-d-state-free antimony single atom (SbSA) on g-C 3 N 4 is more active and stable in the rate-determining water oxidation step, and it also shows a two-electron oxygen . Am. Eur. Am. : Ultrathin platinum nanowires grown on single-layered nickel hydroxide with high hydrogen evolution activity. Bioinspired engineering of cobalt-phosphonate nanosheets for robust hydrogen evolution reaction. Metal complexes that can exist in two different charge distributions often exhibit dramatic color changes when switched between them. Nat. ACS Catal. 2,4 Because our approach cannot describe inelastic . 2, 79337947 (2012). : Rh single atoms on TiO2 dynamically respond to reaction conditions by adapting their site. Angew. : Porous core-shell Fe3C embedded N-doped carbon nanofibers as an effective electrocatalysts for oxygen reduction reaction. X-ray diffraction patterns (XRD, XTRA, Switzerland) were collected to characterize the crystal structures of samples. Chem. https://doi.org/10.1038/s41929-018-0063-z, Li, Z., Chen, Y.J., Ji, S.F., et al. J. Chem. Mater. Adv. Ed. https://doi.org/10.1021/acs.chemrev.7b00776, Article 8, 1490 (2017). Energy Mater. Catal. Catal. 60, 32123221 (2021). Chem. 2, 134141 (2019). Sci. Light-emitting tridentate cyclometalated platinum(ii) complexes containing -alkynyl auxiliaries: tuning of photo- and electrophosphorescence. Am. Valence electrons are the basis of all chemical bonds. https://doi.org/10.1002/adma.201802880, Levy, R.B., Boudart, M.: Platinum-like behavior of tungsten carbide in surface catalysis. : Enhancing hydrogen evolution activity in water splitting by tailoring Li+-Ni(OH)2Pt interfaces. https://doi.org/10.1002/anie.201903882, Mitchell, R.W., Lloyd, D.C., van de Water, L.G.A., et al. Soc. 58, 1603816042 (2019). : An approach to understanding the electrocatalytic activity enhancement by superexchange interaction toward OER in alkaline media of Ni-Fe LDH. Chem. Mater. All the samples were first exposed to H2 for 2 h before their XPS spectra were collected. 10, 4876 (2019). Rev. 12, 28902923 (2019). Nat. Chem. Ed. Reproduced with permission. Mater. Sci. Adv. https://doi.org/10.1039/d0ta02425b, Deng, D.H., Chen, X.Q., Yu, L., et al. Wang, X. et al. Li, B. et al. https://doi.org/10.1002/anie.201308245, Lu, J., Elam, J.W., Stair, P.C. Phys. : Single platinum atoms embedded in nanoporous cobalt selenide as electrocatalyst for accelerating hydrogen evolution reaction. 18, 12151221 (2019). Despite substantial experimental evidence of electron transfer, atom exchange, and mineralogical transformation during the reaction of Fe (II) aq with synthetic Fe (III) minerals, these processes are rarely investigated in natural soils. Chem. Ed. Mater. Science 335, 12051208 (2012). https://doi.org/10.1038/ncomms2929, Huang, F., Deng, Y.C., Chen, Y.L., et al. 75, 46 (1999). ONE individual atom, a purely . Mater. 122, 375379 (1985). https://doi.org/10.1021/acs.jpcc.8b00078, Li, B.Q., Zhao, C.X., Chen, S.M., et al. Chem. Nat. Soc. Rev. Chem. : Ultrahigh-current-density niobium disulfide catalysts for hydrogen evolution. CHE 105/110 - Introduction to Chemistry - Textbook Brooks, J. et al. Campbell, C. T. Electronic perturbations. Am. https://doi.org/10.1021/jacs.7b07093, Lin, X., Nilius, N., Sterrer, M., et al. 131, 1199411999 (2019). Nat. : Stabilizing platinum atoms on CeO2 oxygen vacancies by metal-support interaction induced interface distortion: mechanism and application. Design of active and stable CoMoSx chalcogels as pH-universal catalysts for the hydrogen evolution reaction. : Design of a surface alloy catalyst for steam reforming. Ed. ADS Luminescent platinum(ii) complexes of 1,3-bis(N-alkylbenzimidazol-2-yl)benzene-type ligands with potential applications in efficient organic light-emitting diodes. : Atomic-level tuning of Co-N-C catalyst for high-performance electrochemical H2O2 production. 100, 170175 (1978). https://doi.org/10.1016/j.chempr.2017.04.001, Chang, S.H., Connell, J.G., Danilovic, N., et al.

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in electron transfer involving a metallic atom and an